Product ID:PYROIL SUVA TRANS A/C 15 LB CYLINDER
MSDS Date:02/10/1995
FSC:9150
NIIN:00N083378
MSDS Number: CGQFS

VALVOLINE CO

LEXINGTON, KY 40512
US

Emergency Phone: 800-274-5263

Info Phone: 606-264-7000

Cage: IO754

VALVOLINE OIL CO

14000 LEXINGTON, KY 40512 US

Telephone: 606-357-7206 / 800-274-5263

Cage: 72527

ETHANE, 1,1,1,2-TETRAFLUORO; (1,1,1,2-TETRAFLUOROETHANE)

CAS: 811-97-2

RTECS: KI8842500

Fraction By Weight: 100%

OSHA PEL N/K

ACGIH TLV: N/K

IF SYMPTOMS DEVELOP, IMMED MOVE INDIVIDUAL

RTECS: 9999999ZZ

ATTN; KEEP PERSON WARM & QUIET. IF PERSON IS NOT

RTECS: 9999999ZZ

INHALATION OF HIGH

RTECS: 9999999ZZ

ENCLOSED SPACES OR DURING DELIBERATE ABUSE, MAY BE

RTECS: 9999999ZZ

DRUGS MAY INITIATE CARDIAC ARRHYTHMIAS IN PERSONS

RTECS: 9999999ZZ

(NEGATIVE PRESSURE TYPE) UNDER SPECIFIED

RTECS: 9999999ZZ

ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO

RTECS: 9999999ZZ

& FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: EXPOSURE CAUSES EYE IRRIT. SYMPS
MAY INCLUDE STINGING, TEARING, REDNESS & SWELLING. SKIN: EXPOSURE
MAY CAUSE BURNS & FROSTBITE. INGEST: SINGLE DOSE ORAL TOXICITY IS
LOW. SWALLOWING SMALL AMTS DU RING NORMAL HANDLING IS NOT LIKELY TO
CAUSE HARMFUL EFFECTS; SWALLOWING LARGE AMOUNTS MAY BE HARMFUL.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: GI IRRITATION (NAUSEA, VOMITING,
DIARRHEA). INHAL: EXPOSURE TO VAP/MIST IS POSSIBLE. SHORT-TERM
INHAL TOXICITY IS LOW. BREATHING SMALL AMTS DURING NORMAL HANDLING
IS NOT LIKELY TO CAUSE HARM FUL EFFECTS; BREATHING LARGE AMTS MAY
BE HARMFUL. IRRITATION (NOSE, THROAT, RESPIRATORY TRACT). CNS
DEPRESSION (SUPDAT)
Medical Cond Aggravated by Exposure:PRE-EXISTING LUNG DISORDERS, EG
ASTHMA-LIKE CONDITIONS, MAY BE AGGRAVATED BY EXPOSURE TO THIS
MATERIAL.

First Aid:EYES: IF MATERIAL GETS INTO EYES, IMMED FLUSH EYES GENTLY
W/WATER FOR AT LEAST 15 MIN WHILE HOLDING EYELIDS APART. IF
SYMPTOMS DEVELOP AS RESULT OF VAPOR EXPOSURE, IMMED MOVE INDIVIDUAL
AWAY FROM EXPO SURE & INTO FRESH AIR BEFORE FLUSHING AS RECOMMENDED
ABOVE. SEEK IMMED MED ATTN. SKIN: TREAT BURNED OR FROSTBITTEN SKIN
BY FLUSHING EXPOSED AREA W/LUKEWARM WATER. SEEK IMMED MED ATTN.
INGEST: (ING 2)

Extinguishing Media:WATER FOG.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER MAY BE USED TO KEEP FIRE-EXPOSED CNTNRS COOL UNTIL FIRE IS
OUT. REFER TO THE PERSONAL PROT EQUIP OF MSDS.
Unusual Fire/Explosion Hazard:HFC-134A IS NOT FLAMMABLE AT AMBIENT
TEMPS & ATMOSPHERIC PRESSURE. HOWEVER, HFC-134A HAS BEEN SHOWN IN
TESTS TO BE COMBUSTIBLE AT PRESS AS LOW AS 5.5 (SUPDAT)

Spill Release Procedures:SMALL SPILL: ALLOW TO EVAPORATE. VENTILATE
AREA. LARGE SPILL: ALLOW TO EVAPORATE. PERSONS NOT WEARING
PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA UNTIL LEAK HAS
BEEN REPORTED.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORAGE: NOT APPLICABLE.
Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR,
LIQUID AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THE DATA
SHEET MUST BE OBSERVE D.

Respiratory Protection:IF WORKPLACE EXPOSURE LIMIT(SP) OF PRODUCT OR
ANY COMPONENT IS EXCEEDED, A NIOSH APPROVED AIR SUPPLIED RESPIRATOR
IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REGS
ALSO PERMIT OTHER NIO SH APPROVED RESPIRATORS (ING 7)
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:RESISTANT SUCH AS POLYVINYL ALCOHOL.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 9)
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR NORMAL WORK CLOTHING COVERING ARMS & LEGS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ: PSIG (AT 177C;350.6F) WHEN MIXED W/AIR AT CONCENTRATIONS OF
GENERALLY MORE THAN 60 VOLUME % AIR. AT LOWER TEMPS, HIGHER
PRESSURES ARE REQD FOR COMBUSTIBILITY. EFTS OF OVEREXP: (DIZZINESS,
D ROWSINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE, UNCONSCIOUSNESS)
& DEATH.

Boiling Pt:B.P. Text:-16F,-27C
Vapor Pres:4964 @ 77F
Vapor Density:3.180
Spec Gravity:1.210
Evaporation Rate & Reference:FASTER THAN ETHYL ETHER
Appearance and Odor:CLEAR LIQUID.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH ALKALI METALS, POWDERED METALS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FORM CARBONYL FLUORIDE, HYDROGEN
FLUORIDE.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS . RETURN TO SUPPLIER FOR RECLAMATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.